top of page

最新論文
Latest Publications

Nickel-Photoredox-Catalyzed Stereoconvergent Coupling of Alkenyl Halides and Nitrogen-Containing Heterocycles

Sodai Nishino, Kô Sudo, and Takuya Kurahashi*

Org. Lett. 2024, volume, page–page (Just Accepted). 

​

​アゾールラジカルの生成を活用したカップリング反応

発表論文

Ni-Photoredox-catalyzed Amide Arylation Reaction Using Amidyl Radical Formation via PCET

Sodai Nishino and Takuya Kurahashi*

Chem. Lett. 2024, volume, page–page (Just Accepted). 

​

アミジルラジカルの生成を活用したカップリング反応

最新論文

​原著論文
Publications

  1. “Carbostannylation of Alkynes Catalyzed by an Iminophosphine-Palladium Complex” Shirakawa, E.; Yoshida, H.; Kurahashi, T.; Nakao, Y.; Hiyama, T. J. Am. Chem. Soc. 1998, 120, 2975.

  2. “Palladium-Iminophosphine-Catalyzed Alkynylstannylation of Alkynes” Yoshida, H.; Shirakawa, E.; Kurahashi, T.; Nakao, Y.; Hiyama, T. Organometallics 2000, 19, 5671. 

  3. “Diphenylphosphinophenolate: a Ligand for the Palladium-Catalyzed Silylation of Aryl Halides Activating Simultaneously both Palladium and Silicon” Shirakawa, E.; Kurahashi, T.; Yoshida, H.; Hiyama, T. Chem. Commun. 2000, 1895. 

  4. “Geminal Difunctionalization of Alkenylidene-Type Carbenoids by Using Interelement Compounds” Hata, T.; Kitagawa, H.; Masai, H.; Kurahashi, T.; Shimizu, M.; Hiyama, T. Angew. Chem. Int. Ed. 2001, 40, 790.

  5.  “Novel Synthesis of 2,3-Bisboryl-1,3-dienes from 1-Bromo-1-lithioethene and 1,1-Bisborylalkenes” Shimizu, M.; Kurahashi, T.; Hiyama, T. Synlett, 2001, 1006. 

  6.  “1-Silyl-1-boryl-2-alkenes: Reagents for Stereodivergent Allylation Leading to 4-Oxy-(E)-1- alkenylboronates and 4-Oxy-(Z)-1-alkenylsilanes” Shimizu, M.; Kitagawa, H.; Kurahashi, T.; Hiyama, T. Angew. Chem. Int. Ed. 2001, 40, 4283. 

  7.  “Geminal Dimetalation of Alkylidene-Type Carbenoids with Silylboranes and Diborons” Kurahashi, T.; Hata, T.; Masai, H.; Kitagawa, H.; Shimizu, M.; Hiyama, T. Tetrahedron 2002, 58, 6381. 

  8. “gem-Silylborylation Approach for Tri- and Tetrametalmethanes: The First Synthesis of Boryl(germyl)(silyl)(stannyl)methanes” Shimizu, M.; Kurahashi, T.; Shimono, K.; Hiyama, T. J. Organomet. Chem. 2003, 686, 286. 

  9. “gem-Silylborylation of an sp Carbon: Novel Synthesis of 1-Boryl-1-silylallenes” Shimizu, M.; Kurahashi, T.; Kitagawa, H.; Hiyama, T. Org. Lett. 2003, 5, 225. 

  10. “Facile Synthesis of Dendralenes Based on the Cross-coupling Reaction of 2,3-Bis(pinacolato)boryl-1,3-butadiene” Shimizu, M.; Tanaka, K.; Kurahashi, T.; Shimono, K.; Hiyama, T. Chem. Lett. 2004, 33, 1066. 

  11. “Stereoselective Cross-Coupling Reaction of 1,1-Diboryl-1-alkenes with Electrophiles: A Highly Stereocontrolled Approach to 1,1,2-Triaryl-1-alkenes” Shimizu, M.; Nakamaki, C.; Shimono, K.; Schelper, M.; Kurahashi, T.; Hiyama, T. J. Am. Chem. Soc. 2005, 127, 12506.

  12. “Cyclopentenones from a Novel [4+1] Cocyclization of Methylenecyclopropanes with Fischer Carbenechromium Complexes” Kurahashi, T.; de Meijere, A. Synlett, 2005, 805.

  13. “[5+1] Cocyclization of (Cyclopropylmethylene)cyclopropanes and Other Vinyl-Cyclopropanes with Carbon Monoxide Catalyzed by Octacarbonyldicobalt” Kurahashi, T.; de Meijere, A. Synlett, 2005, 2619. 

  14. “Cyclopropyl Building Blocks for Organic Synthesis, Part 121. C–C Bond Activation by Octacarbonyldicobalt: [3+1] Cocyclizations of Methylenecyclopropanes with Carbon Monoxide” Kurahashi, T.; de Meijere, A. Angew. Chem. Int. Ed. 2005, 44, 7881.　

  15. “Synthesis and Applications of 1,1-Diborylated Cyclopropanes: Facile Route to 1,2-Diboryl-3-methylenecyclopentenes” Shimizu, M.; Nagao, I.; Shimono, K.; Kurahashi, T.; Hiyama, T. Chem. Lett. 2006, 35, 1222.

  16. “Syntheses and Properties of Enantiomerically Pure Higher (n > 7) n-2 Triangulanedimethanols and σ- [n] Helicenes” de Meijere, A.; Khlebnikov, A. E.; Kozhushkov, S. I; Kurahashi, T.; Miyazawa, K. Chem. Euro. J. 2006, 12, 5697.

  17. “Intermolecular Rhodium-Catalyzed Carbometalation/Heck-Type Reaction in Water” Kurahashi, T.; Shinokubo, H.; Osuka, A. Angew. Chem. Int. Ed. 2006, 45, 6336.
    Highlighted in Organic Chemistry Portal.

  18. “1,1'-Linked Cyclopropane Derivatives: The Helical Conformation of Quinquecyclopropanol” Kurahashi, T.; Kozhushkov, S. I.; Schill, H.; Meindl, K.; Ruhl, S.; de Meijere, A. Angew. Chem. Int. Ed. 2007, 46, 6545.

  19. “Facile Synthesis and Palladium-Catalyzed Cross-Coupling Reactions of 2,3-Bis(pinacolatoboryl)-1,3-butadiene” Shimizu, M.; Kurahashi, T.; Nagao, I.; Kiyomoto, S. I.; Hiyama, T. Chem. Asia J. 2007, 2, 1400.

  20. “Diels-Alder Reaction of 2,3-Bis(pinacolatoboryl)-1,3-butadiene: Facile Preparation of 1,2-bis(pinacolatoboryl)cyclohexenes and-1,4-cyclohexadiene” Shimizu, M.; Shimono, K.; Kurahashi, T.; Nagao, I.; Hiyama, T. Bull. Chem. Soc. Jp. 2008, 81, 518.

  21. “Nickel-Catalyzed Decarbonylative Addition of Phthalimides to Alkynes” Kajita, Y.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2008, 130, 6058.   
    Highlighted as the Most Read Articles.
    Highlighted in SYNFACTS, 2008, 764.

  22. “Nickel-Catalyzed Decarbonylative Addition of Anhydrides to Alkynes” Kajita, Y.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2008, 130, 17226.
    Highlighted as the Most Read Articles.

  23. “Diastereoselective Nucleophilic Cyclopropanation of 1,2-Diketones and α-Ketoimines with Bis(iodozincio)methane” Nomura, K.; Asano, K.; Kurahashi, T.; Matsubara, S. Heterocycles 2008, 76, 1381.

  24. “Nickel-Catalyzed [4+2] Cycloaddition of Enones with Alkynes” Koyama, I.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2009, 131, 1350.    

  25. “Nickel-Catalyzed Decarboxylative Carboamination of Alkynes with Isatoic Anhydrides” Yoshino, Y.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2009, 131, 7494.   
    Highlighted in SYNFACTS, 2009, 833.

  26. “Nickel-Catalyzed Cycloaddition of Salicylic acid Ketals to Alkynes via Elimination of Ketones” Ooguri, A.; Nakai, K.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2009, 131, 13194.  
    Highlighted as the Most Read Articles.

  27. “Nickel-Catalyzed [4+2] Cycloaddition of Alkynes to Carbonylsalicylamides via Elimination of Isocyanates”  Yoshino, Y.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2010, 39, 896.

  28. “Decarbonylative Cycloaddition of Phthalimides with 1,3-Dienes” Fujiwara, K.; Kurahashi, T.; Matsubara, S. Org. Lett. 2010, 12, 4548. 

  29. “Selective Synthesis of Trienes and Dienes via Nickel-Catalyzed Intermolecular Cotrimerization of Acrylates and Alkynes” Horie, H.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2010, 46, 7229. 

  30. “Nickel-Catalyzed [2+2+1] Cycloaddition of Alkynes, Acrylates and Isocyanates” Ozawa, T.; Horie, H.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2010, 46, 8055.

  31. “Nickel-Catalyzed Decarbonylative Cycloaddition of Phthalic Anhydrides with 1,3-Diene” Fujiwara, K.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2011, 40, 322. 

  32. “Nickel-Catalyzed Cycloadditions of Benzoxazinones with Alkynes: Synthesis of Quinolines and Quinolones” Maizuru, N.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2011, 40, 375. 

  33. “Nickel-Catalyzed Cycloaddition of Anthranilic Acid Derivatives to Alkynes” Maizuru, N.; Inami, T.; Kurahashi, T.; Matsubara, S. Org. Lett. 2011, 13, 1206. 

  34. “Nickel-Catalyzed Cycloadditions of Thiophthalic Anhydrides with Alkynes” Inami, T.; Kurahashi, T.; Matsubara, S. Org. Lett. 2011, 13, 1912.

  35. “Decarbonylative Cycloaddition of Phthalic Anhydrides with Allenes” Ochi, Y.; Kurahashi, T.; Matsubara, S. Org. Lett. 2011, 13, 1374.     

  36. “Nickel-Catalyzed Intermolecular Codimerization of Acrylates and Alkynes” Horie, H.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2011, 47, 2658. 

  37. “Nickel-Iminophosphine-Catalyzed [4+2] Cycloaddition of Enones with Allenes: Synthesis of Highly Substituted Dihydropyrans” Sako, S.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2011, 47, 6150.

  38. “Nickel-Catalyzed [3 + 2] Cycloaddition of a,b-Unsaturated Ketones with Vinyloxiranes“ Sako, S.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2011, 40, 808.

  39.  “Nickel-Catalyzed Cycloaddition of o-Arylcarboxybenzonitriles and Alkynes via Cleavage of Two Carbon–Carbon s Bonds“ Nakai, K.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2011, 133, 11066.
    Highlighted as the Most Read Articles.
    Highlighted in SYNFACTS, 2011, 1065.

  40. “Nickel-Catalyzed Cycloaddition of Aromatic (O-Benzyl)Ketoximes with Alkynes to Produce Isoquinoline and Isoquinoline N-Oxide Derivatives” Yoshida, Y.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2011, 40, 1140.
    Highlighted as Editor’s Choice Article.

  41. “Methylenecyclopropanes in [4 + 1] Cycloaddition with Enones” Inami, T.; Sako, S.; Kurahashi, T.; Matsubara, S. Org. Lett. 2011, 13, 3837.

  42. “Dehydrogenative Diels-Alder Reaction” Ozawa, T.; Kurahashi, T.; Matsubara, S. Org. Lett. 2011, 13, 5390.

  43. “Nickel-Catalyzed Heteroannulation of o-Haloanilines with Alkynes” Yoshida, Y.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2011, 40, 1067.

  44. “Nickel-Catalyzed Decarboxylative Polymerization of 6-Alkynyl Isatoic Anhydride” Yoshino, Y.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2011, 40, 1240.

  45. “Methylenecyclopropane as C1 Synthetic Units: [1 + 4] Cycloaddition by Nickel Catalyst” Inami, T.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2011, 47, 9711.

  46. “Nickel-Catalyzed Cycloaddition of α,β,γ,δ-Unsaturated Ketones with Alkynes” Horie, H.; Kurahashi, T.; Matsubara, S. Angew. Chem. Int. Ed. 2011, 50, 8956. 
    Highlighted as Hot Paper.

  47. “Nickel-Catalyzed [4+2] Cycloaddition for Highly Substituted Arenas” Horie, H.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2012, 48, 3866.
    Highlighted in ChemistryViews.

  48. “Cationic Iron(III) Porphyrin Catalyzed [4+2] Cycloaddition of Unactivated Aldehydes with Simple Dienes” Fujiwara, K.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2012, 134, 5512.
    Highlighted as the Most Read Articles.
    Highlighted as Synfact of the Month in SYNFACTS, 2012, 625.
    解説記事掲載　化学 2012年10月号59頁.

  49. “Manganese Porphyrin Catalyzed Cycloisomerization of Enynes” Ozawa, T.; Kurahashi, T.; Matsubara, S. Org. Lett. 2012, 14, 5390.
    Highlighted as the Most Read Articles.

  50. “Nickel-Catalyzed Cycloaddition of α,β-Unsaturated Oximes with Alkynes; Synthesis of Highly Substituted Pyridine Derivatives” Yoshida, Y.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2012, 41, 1498.
    Highlighted as Editor’s Choice Article.

  51. “Ruthenium Porphyrin Catalyzed Friedel–Crafts Type Reaction of Arenes with Imines” Terada, T.; Kurahashi, T.; Matsubara, S. Heterocycles 2012, 80, 2415.

  52. “Nickel-Catalyzed Decarbonylative Polymerization of 5-Alkynyl Phthalimides: a New Methodology for Preparation of Polyheterocycles” Takeuchi, M.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2012, 41, 1566.

  53. “Cobalt(III) Porphyrin Catalyzed Aza-Diels–Alder Reaction”  Wakabayashi, R.; Kurahashi, T.; Matsubara, S. Org. Lett. 2012, 14, 4794.

  54. “Nickel-Catalyzed Decarbonylative Alkylidenation of Phthalimides with Trimethylsilyl-Substituted Alkynes” Shiba, T.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2013, 135, 13636.  
    Highlighted as the Most Read Articles.

  55. “Synthesis of Quinolones by Nickel-Catalyzed Cycloaddition via Elimination of Nitrile” Nakai, K.; Kurahashi, T.; Matsubara, S. Org. Lett. 2013, 15, 856.

  56. “Nickel-Catalyzed Cycloaddition of Vinylcyclopropanes to Imines” Tombe, R.; Kurahashi, T.; Matsubara, S. Org. Lett. 2013, 15, 1791.
    Highlighted as the Most Read Articles.

  57. “Nickel-Catalyzed Decarbonylative /Decarboxylative Cycloaddition of Isatoic Anhydrides with Alkynes” Nakai, K.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2013, 42, 1238.

  58. “Cationic Iron(III) Porphyrin Catalyzed Dehydrative Friedel–Crafts Reaction of Alcohols with Arenes” Teranishi, S.; Kurahashi, T.; Matsubara, S. Synlett, 2013, 24, 2148.

  59. “Iron Corrole-Catalyzed [4+2] Cycloaddition of Dienes and Aldehydes” Kuwano, T.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2013, 42, 1241.

  60. “Synthesis of Phenanthrenes by Cationic Chromium(III) Porphyrin-Catalyzed Dehydration Cycloaromatization” Wakabayashi, R.; Kurahashi, T.; Matsubara, S. Synlett, 2013, 24, 2297.

  61. “[3+2] Cycloaddition of Aziridines with Alkenes Catalyzed by Cationic-Manganese-Porphyrin” Ozawa, T.; Kurahashi, T.; Matsubara, S. Synlett, 2013, 24, 2763.
    Highlighted in Organic Chemistry Portal.

  62. “Dicationic Platinum Porphyrin Catalyzed Cycloisomerization of Enynes” Hasegawa, M.; Kurahashi, T.; Matsubara, S. Tetrahedron Lett. 2013, 54, 6196.

  63. “Theoretical Mechanistic Study of Novel Ni(0)-Catalyzed [6-2+2] Cycloaddition Reactions of Isatoic Anhydrides with Alkynes: Origin of Facile Decarboxylation” Guan, W.; Sakaki, S.; Kurahashi, T.; Matsubara, S. Organometallics 2013, 32, 7564.

  64. “Nickel-Catalyzed Redox-Economical Coupling of Alcohols and Alkynes to Form Allylic Alcohols” Nakai, K.; Yoshida, Y.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2014, 136, 7797.
    Highlighted as the Most Read Articles.
    解説記事掲載　日経産業新聞　平成27年9月24日.

  65. “Diastereoselective Construction of Trans-Fused Octalone Framework via Ruthenium-Porphyrin-Catalyzed Cycloaddition” Terada, T.; Kurahashi, T.; Matsubara, S. Org. Lett. 2014, 16, 2594–2597.
    Highlighted as the Most Read Articles.
    Highlighted in SYNFACTS, 2014, 715.

  66. “Palladium Porphyrin Catalyzed Hydrogenation of Alkynes: Stereoselective Synthesis of cis-Alkenes” Nishibayashi, R.; Kurahashi, T.; Matsubara, S. Synlett, 2014, 25, 1287.
    Highlighted in Organic Chemistry Portal.

  67. “Rh(III) Porphyrin-Catalyzed Reactions via Activation of Alkynes” Hasegawa, M.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2014, 43, 1287.

  68. “Cobalt Porphyrin Catalyzed [3+2] Cycloaddition of Cyclopropanes and Carbonyl Compounds” Shiba, T.; Kurahashi, T.; Matsubara, S. Synlett, 2014, 25, 2005.

  69. “Regio- and Diastereoselective Nickel-Catalyzed Cycloaddition of Activated Cyclopropanes with Allenes” Tombe, R.; Iwamoto, T.; Kurahashi, T.; Matsubara, S. Synlett, 2014, 25, 2281.
    Highlighted as a Cluster Article.

  70. “Ruthenium-Porphyrin-Catalyzed [4+2] Cycloaddition of a,b-Unsaturated Imines and Aldehydes” Maeda, K.; Terada, T.; Iwamoto, T.; Kurahashi, T.; Matsubara, S. Org. Lett. 2015, 17, 5284.

  71. “Nickel-Catalyzed Dual C-C σ Bond Activation to Construct Carbocyclic Skeletons” Nakai, K.; Kurahashi, T.; Matsubara, S. Tetrahedron, 2015, 71, 4512.

  72. “Reasons Two Nonstrained C-C σ-Bonds Can Be Easily Cleaved in Decyanative [4+2] Cycloaddition Catalyzed by Nickel(0)/Lewis Acid Systems. Theoretical Insight” Gua, W.; Sakaki, S.; Kurahashi, T.; Matsubara, S. ACS Catal. 2015, 5, 1.  

  73. “Nickel-Catalysed Synthesis of Tetrasubstituted Vinyl Sulfides from Thiocarbamates and Internal Alkynes” Inami, T.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2015, 51, 1285.

  74. “A Triphenylamine with Two Phenoxy Radicals Having Unusual Bonding Patterns and a Closed-Shell Electronic State” Sakamaki, D.; Yano, S.; Kobashi, T.; Seki, S.; Kurahashi, T.; Matsubara, S.; Ito, A. Angew. Chem. Int. Ed. 2015, 28, 8267. 

  75. “Nickel-Catalyzed Intermolecular Carboiodination of Alkynes with Aryl Iodides” Takahashi, T.; Kuroda, D.; Kuwano, T.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2018, 54, 12750. 
    Highlighted in Chemistry Views.

  76. “Ligand-Controlled Behavior of Ag(I)-π Complex as σ-Lewis Acid” Maeda, K.; Takahashi, T.; Tomifuji, R.; Hirao, N.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2018, 47, 532. 

  77. “FeCl3 as an Ion-Pairing Lewis Acid Catalyst. Formation of Highly Lewis Acidic FeCl2+ and Thermodynamically Stable FeCl4– To Catalyze the Aza-Diels–Alder Reaction with High Turnover Frequency” Tomifuji, R.; Maeda, K.; Takahashi, T.; Kurahashi, T.; Matsubara, S. Org. Lett. 2018, 20, 7474. 
    Highlighted in Organic Chemistry Portal.

  78. “Diastereoselective Synthesis of 1,3-Oxazolidines via Cationic Iron Porphyrin-catalyzed Cycloaddition of Aziridines with Aldehydes” Teranishi, S.; Maeda, K.; Kurahashi, T.; Matsubara, S. Org. Lett. 2018, 20, 2593.
    Highlighted in Organic Chemistry Portal.

  79. “Cationic Cobalt Porphyrin-Catalyzed Allylation of Aldehydes with Allyltrimethylsilanes” Tomifuji, R.; Masuda, S.; Kurahashi, T.; Matsubara, S. Org. Lett. 2019, 21, 3834.

  80. “Asymmetric Aza‐Diels–Alder Reaction with Ion‐Paired—Iron Lewis Acid—Brønsted Acid Catalyst” Tomifuji, R.; Kurahashi, T.; Matsubara, S. Chem. Eur. J. 2019, 25, 8987.
    Highlighted as Hot Paper.
    Highlighted in SYNFACTS, 2019, 1231.

  81. “Chlorotrifluoromethylation of Terminal Olefins by Atom Transfer-Type Radical Reaction Catalyzed by Cobalt Complexes” Maeda, K.; Kurahashi, T.; Matsubara, S. Eur. J. Org. Chem. 2019, 4613.

  82. “Nickel-Catalyzed [5+2] Cycloaddition of 10π-Electron Aromatic Benzothiophenes with Alkynes To Form Thermally Metastable 12π-Electron Nonaromatic Benzothiepines” Inami, T.; Takahashi, T.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2019, 141, 12541.

  83. “Nickel-Catalyzed Intermolecular Carbobromination of Alkynes” Takahashi, T.; Kurahashi, T.; Matsubara, S. ACS Catal. 2020, 10, 3773.

  84. “Cu(II) Porphyrin-Catalyzed Coupling of Alkyl Tosylates and Grignard Reagents” Matsuoka, I.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2020, 49, 442.

  85. “Synthesis, Characterization and Chemical Behavior of Disulfide-Bearing Mononuclear Transition Metal Complexes with the Rigid Structure” Maeda, K.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2021, 50, 1883.

  86. “Catalytic Aerobic Oxidation of Alkenes with Ferric Boroperoxo Porphyrin Complex; Reduction of Oxygen by Iron Porphyrin” Kimura, K.; Murano, S.; Kurahashi, T.; Matsubara, S. Bull. Chem. Soc. Jp. 2021, 94, 2493.
    Highlighted as Selected Paper.

  87. “Ni-Catalyzed Dearomative Cycloaddition of Alkynes to 10π Aromatic Benzothiophenes: Elucidation of Reaction Mechanism” Takahashi, T.; Kurahashi, T.; Matsubara, S. Bull. Chem. Soc. Jp. 2021, 94, 2727.
    Highlighted as BSCJ Award Article.

  88. “Multiple Activation Catalyst for Asymmetric [4 + 2] Cycloaddition of Aldehydes with Dienes” Tomifuji, R.; Murano, S.; Teranishi, S.; Kuroda, D.; Kurahashi, T.; Matsubara, S. Synlett, 2021, 32, 1943.
    Nominated to the SYNLETT Best Paper Award.

  89. “A New Synthetic Route to (Trifluoromethyl)quinolines: Nickel-Catalyzed Insertion of an Alkyne into an Aromatic C–S Bond by Formation of a Thianickelacycle and Thermal Desulfidation” Inami, T.; Kurahashi, T.; Matsubara, S. Synlett, 2021, 32, 1948.
    Highlighted in Synform.

  90. “FeBr3-Catalyzed Fully Intermolecular [2+2+2] Cycloaddition of Alkenes” Tomifuji, R.; Murano, S.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2021, 12, 2018.

  91. “Aerobic Direct Dioxygenation of Terminal/Internal Alkynes to α-Hydroxyketones by an Fe Porphyrin Catalyst” Kimura, K.; Kurahashi, T.; Matsubara, S. Chem. Eur. J. 2021, 16, 3615.

総説
Reviews

  1. “Novel Bifunctional Synthetic Reagents: gem-Dimetallic Compounds Derived from Carbenoid Reagents and Interelement Compounds” Shimizu, M.; Kurahashi, T.; Hiyama, T. J. Syn. Org. Chem. Jp. 2001, 59, 1062.

  2. “Applications of Fischer Carbenemetal Complexes in Organic Synthesis.” Wu, Y. T.; Kurahashi, T.; de Meijere, A. J. Organomet. Chem. 2005, 690, 5900.

  3. “Syntheses of Heterocycles by Nickel-catalyzed Substitution Reaction-Development of [6-2+2] Reaction” Matsubara, S.; Kurahashi, J. Syn. Org. Chem. Jp. 2010, 68, 33.

  4. “Ni-Catalyzed C–C Bond Formation with α,β-Unsaturated Carbonyl Compounds and Alkynes” Kurahashi, T. Bull. Chem. Soc. Jpn. 2014, 87, 1058. 

  5. “Nickel-Catalyzed Reactions Reactions Directed toward the Formation of Heterocycles” Matsubara, S.; Kurahashi, T. Acc. Chem. Res. 2015, 48, 1703.
     

著書
Books and Chapters

  1. “Simultaneous C–C and Other Bond Formation” A. de Meijere and T. Kurahashi, Comprehensive Organometallic Chemistry, Vol. 11, Pergamon Press, 2005.

  2. “[4+2] Cycloaddition via Metallacycles” T. Kurahashi and S. Matsubara, Transition-Metal-Mediated Aromatic Ring Construction, Wiley, 2012. 
     

bottom of page