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最新論文
Latest Publications

Nickel-Catalyzed Enantioconvergent Cycloadditions of Aziridines and Imines

Toshifumi Takahashi, Rihoko Tonbe, Daishi Hiramatsu, and Takuya Kurahashi

Synlett, 2025, 36, just accepted.

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ニッケル触媒による立体収束的環化付加反応

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Polarity Inversion Strategy for Nickel-Catalyzed Reductive Coupling of Aldehydes with Alkenyl Halides

Shuto Odagaki , Ko Sudo, Kosuke Kawabe, and Takuya Kurahashi

Synlett, 2025, 36, just accepted.

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アルデヒドとアルケニルハライドの還元的クロスカップリング反応

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Coupling Reaction of Aryl Halides with Orthoformate Ester

Saki Shigemura and Takuya Kurahashi

Synlett, 2025, 36, 894.

Article selected by the Editorial Board for the cover graphic

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オルトギ酸エステルからのラジカル生成を活用したカップリング反応

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Nickel-Photoredox-Catalyzed Stereoconvergent Coupling of Alkenyl Halides and Nitrogen-Containing Heterocycles

Sodai Nishino, Kô Sudo, and Takuya Kurahashi

Org. Lett., 2024, 26, 4049. 

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​アゾールラジカルの生成を活用したカップリング反応

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Ni-Photoredox-catalyzed Amide Arylation Reaction Using Amidyl Radical Formation via PCET

Sodai Nishino and Takuya Kurahashi

Chem. Lett, 2024, 53, upae088. 

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アミジルラジカルの生成を活用したカップリング反応

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Photoredox-Catalyzed S-Alkenylation of Benzenethiols with Alkenyl Halides

Sodai Nishino and Takuya Kurahashi

Chem. Lett, 2024, 53, upae157. 

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チオフェノールとアルケニルハライドのカップリング反応

Nishino_PhSH.png

Nickel-Photoredox-Catalyzed E- and Z-Stereoconvergent Coupling of Alkenyl Halides and Phenols

Sodai Nishino and Takuya Kurahashi

Chem. Lett, 2024, 53, upae111. 

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フェノールとアルケニルハライドの立体収束的カップリング反応

Nishino_PhOH copy.png

Aerobic Direct Dioxygenation of Terminal/Internal Alkynes to α-Hydroxyketones by an Fe Porphyrin Catalyst

Kento Kimura, Takuya Kurahashi, and Seijiro Matsubara

Chem. Asian J. 2021, 16, 3615.

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​鉄ポルフィリン触媒によるアルキンの酸化反応

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FeBr3-Catalyzed Fully Intermolecular [2+2+2] Cycloaddition of Alkenes

Rei Tomifuji, Shunpei Murano,Takuya Kurahashi, and Seijiro Matsubara

Chem. Lett. 2021, 12, 2018.

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​鉄触媒による分子間[2+2+2]環化付加反応

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A New Synthetic Route to (Trifluoromethyl)quinolines: Nickel-Catalyzed Insertion of an Alkyne into an Aromatic C–S Bond by Formation of a Thianickelacycle and Thermal Desulfidation

Tasuku Inami, Takuya Kurahashi, and Seijiro Matsubara

Synlett, 2021, 32, 1948.

Highlighted in Synform.

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ニッケル触媒による硫黄原子置換型環化付加反応

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Multiple Activation Catalyst for Asymmetric [4 + 2] Cycloaddition of Aldehydes with Dienes

Rei Tomifuji, Shunpei Murano, Satoru Teranishi, Daiki Kuroda, Takuya Kurahashi, and Seijiro Matsubara

Synlett, 2021, 32, 1943.

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鉄ーキラルリン酸触媒による不斉環化付加反応

88_Synlett, 2021, 32, 1943. copy.png

Ni-Catalyzed Dearomative Cycloaddition of Alkynes to 10π Aromatic Benzothiophenes: Elucidation of Reaction Mechanism

Toshifumi Takahashi, Takuya Kurahashi, and Seijiro Matsubara

Bull. Chem. Soc. Jp. 2021, 94, 2727.

Highlighted as BSCJ Award Article.

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ニッケル触媒による脱芳香族環化付加反応

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Catalytic Aerobic Oxidation of Alkenes with Ferric Boroperoxo Porphyrin Complex; Reduction of Oxygen by Iron Porphyrin

Kento Kimura, Shunpei Murano, Takuya Kurahashi, and Seijiro Matsubara

Bull. Chem. Soc. Jp. 2021, 94, 2493.

Highlighted as Selected Paper.

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鉄ポルフィリン触媒による酸素分子の還元と酸化反応への応用

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Synthesis, Characterization and Chemical Behavior of Disulfide-Bearing Mononuclear Transition Metal Complexes with the Rigid Structure

Kazuki Maeda, Takuya Kurahashi, and Seijiro Matsubara

Chem. Lett. 2021, 50, 1883.

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​含硫黄環状配位子の合成と機能評価

85_Chem. Lett. 2021, 50, 1883. copy.png

Cu(II) Porphyrin-Catalyzed Coupling of Alkyl Tosylates and Grignard Reagents

Iori Matsuoka, Takuya Kurahashi, and Seijiro Matsubara

Chem. Lett. 2020, 49, 442.

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​銅ポルフィリン触媒によるクロスカップリング反応

84_Chem. Lett. 2020, 49, 442 copy.png

Nickel-Catalyzed Intermolecular Carbobromination of Alkynes

Toshifumi Takahashi, Takuya Kurahashi, and Seijiro Matsubara

ACS Catal. 2020, 10, 3773.

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ニッケル触媒によるアルキンのカルボ臭素化反応

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Nickel-Catalyzed [5+2] Cycloaddition of 10π-Electron Aromatic Benzothiophenes with Alkynes To Form Thermally Metastable 12π-Electron Nonaromatic Benzothiepines

Tasuku Inami, Toshifumi Takahashi, Takuya Kurahashi, and Seijiro Matsubara 

J. Am. Chem. Soc. 2019, 141, 12541.

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ニッケル触媒による脱芳香族環化付加反応

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Chlorotrifluoromethylation of Terminal Olefins by Atom Transfer-Type Radical Reaction Catalyzed by Cobalt Complexes

Kazuki Maeda, Takuya Kurahashi, and Seijiro Matsubara

Eur. J. Org. Chem. 2019, 4613.

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コバルトポルフィリン触媒によるアルケンのトリフルオロメチル化反応

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Asymmetric Aza‐Diels–Alder Reaction with Ion‐Paired—Iron Lewis Acid—Brønsted Acid Catalyst

Rei Tomifuji, Takuya Kurahashi, and Seijiro Matsubara

Chem. Eur. J. 2019, 25, 8987.

Highlighted as Hot Paper.
Highlighted in SYNFACTS, 2019, 1231.

 

鉄​ー不斉リン酸触媒による[4+2]環化付加反応

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Cationic Cobalt Porphyrin-Catalyzed Allylation of Aldehydes with Allyltrimethylsilanes

Rei Tomifuji, Shota Masuda, Takuya Kurahashi, and Seijiro Matsubara

Org. Lett. 2019, 21, 3834.

 

コバルトポルフィリン触媒による細見ー桜井反応

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Diastereoselective Synthesis of 1,3-Oxazolidines via Cationic Iron Porphyrin-catalyzed Cycloaddition of Aziridines with Aldehydes

Satoru Teranishi, Kazuki Maeda, Takuya Kurahashi, and Seijiro Matsubara

Org. Lett. 2018, 20, 2593. 

Highlighted in Organic Chemistry Portal.

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鉄ポルフィリン触媒による環化付加反応

78_Org. Lett. 2018, 20, 2593.png

Diastereoselective Synthesis of 1,3-Oxazolidines via Cationic Iron Porphyrin-catalyzed Cycloaddition of Aziridines with Aldehydes

Rei Tomifuji, Kazuki Maeda, Toshifumi Takahashi, Takuya Kurahashi, and Seijiro Matsubara

Org. Lett. 2018, 20, 7474. 

Highlighted in Organic Chemistry Portal.

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鉄触媒による[4+2]環化付加反応

77_Org. Lett. 2018, 20, 7474.png

Ligand-Controlled Behavior of Ag(I)-π Complex as σ-Lewis Acid

Kazuki Maeda, Toshifumi Takahashi, Rei Tomifuji, Naoya Hirao, Takuya Kurahashi, and Seijiro Matsubara

Chem. Lett. 2018, 47, 532. ​

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​銀錯体の合成と応用

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Nickel-Catalyzed Intermolecular Carboiodination of Alkynes with Aryl Iodides

Toshifumi Takahashi, Daiki Kuroda, Toru Kuwano, Yuji Yoshida,  Takuya Kurahashi, and Seijiro Matsubara​

Chem. Commun. 2018, 54, 12750. 

Highlighted in Chemistry Views.

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ニッケル触媒によるアルキンのカルボヨウ素化反応

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Nickel-Catalysed Synthesis of Tetrasubstituted Vinyl Sulfides from Thiocarbamates and Internal Alkynes

Tasuku Inami, Takuya Kurahashi, and Seijiro Matsubara

Chem. Commun. 2015, 51, 1285.​

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ニッケル触媒によるアルキンのチオカルバモイル反応

73_Chem. Commun. 2015, 51, 1285.png

Nickel-Catalysed Synthesis of Tetrasubstituted Vinyl Sulfides from Thiocarbamates and Internal Alkynes

Wei Guan, Shigeyoshi Sakaki, Takuya Kurahashi, and Seijiro Matsubara

ACS Catal. 2015, 5, 1.  ​

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ニッケル触媒を用いる炭素ー炭素結合連続切断による環化付加反応

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Nickel-Catalyzed Dual C-C σ Bond Activation to Construct Carbocyclic Skeletons

Kenichiro Nakai, Takuya Kurahashi, and Seijiro Matsubara​

Tetrahedron, 2015, 71, 4512.

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ニッケル触媒を用いる炭素ー炭素結合連続切断による環化付加反応

71_Tetrahedron, 2015, 71, 4512.png

Ruthenium-Porphyrin-Catalyzed [4+2] Cycloaddition of α,β-Unsaturated Imines and Aldehydes

Kazuki Maeda, Takuma Terada, Takahiro Iwamoto, Takuya Kurahashi, and Seijiro Matsubara​

Org. Lett. 2015, 17, 5284.

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ルテニウムポルフィリン触媒による環化付加反応

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Regio- and Diastereoselective Nickel-Catalyzed Cycloaddition of Activated Cyclopropanes with Allenes

Rihoko Tombe, Takahiro Iwamoto, Takuya Kurahashi, and Seijiro Matsubara​Synlett, 2014, 25, 2281.​

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ニッケル触媒による環化付加反応

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Cobalt Porphyrin Catalyzed [3+2] Cycloaddition of Cyclopropanes and Carbonyl Compounds

Takahiro Shiba, Daiki Kuroda, Takuya Kurahashi, and Seijiro Matsubara

Synlett, 2014, 25, 2005.​​

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コバルトポルフィリン触媒による環化付加反応

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Rh(III) Porphyrin-Catalyzed Reactions via Activation of Alkynes

Makoto Hasegawa, Takuya Kurahashi, and Seijiro Matsubara

Chem. Lett. 2014, 43, 1287.​

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ロジウムポルフィリン触媒による環化付加反応

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Palladium Porphyrin Catalyzed Hydrogenation of Alkynes: Stereoselective Synthesis of cis-Alkenes

Ryo Nishibayashi, Takuya Kurahashi, and Seijiro Matsubara

Synlett, 2014, 25, 1287.​

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パラジウムポルフィリン触媒による水素付加反応

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Diastereoselective Construction of Trans-Fused Octalone Framework via Ruthenium-Porphyrin-Catalyzed Cycloaddition

Takuma Terada, Takuya Kurahashi, and Seijiro Matsubara

Org. Lett. 2014, 16, 2594.​

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ルテニウムポルフィリン触媒による環化付加反応

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Nickel-Catalyzed Redox-Economical Coupling of Alcohols and Alkynes to Form Allylic Alcohols

Kenichiro Nakai, Yuji Yoshida, Takuya Kurahashi, and Seijiro Matsubara

J. Am. Chem. Soc. 2014, 136, 7797.
Highlighted as the Most Read Articles.

日経産業新聞　平成27年9月24日.​

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ニッケル触媒によるカップリング反応

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Theoretical Mechanistic Study of Novel Ni(0)-Catalyzed [6-2+2] Cycloaddition Reactions of Isatoic Anhydrides with Alkynes: Origin of Facile Decarboxylation

Wei Guan, Shigeyoshi Sakaki, Takuya Kurahashi, and Seijiro Matsubara

Organometallics 2013, 32, 7564.

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ニッケル触媒による脱炭酸をともなった環化付加反応

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Dicationic Platinum Porphyrin Catalyzed Cycloisomerization of Enynes

Makoto Hasegawa, Takuya Kurahashi, and Seijiro Matsubara

Tetrahedron Lett. 2013, 54, 6196.​

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白金ポルフィリン触媒による環化異性化反応

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[3+2] Cycloaddition of Aziridines with Alkenes Catalyzed by Cationic-Manganese-Porphyrin

Takuya Ozawa, Takuya Kurahashi, and Seijiro Matsubara

Synlett, 2013, 24, 2763.

Highlighted in Organic Chemistry Portal.​

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マンガンポルフィリン触媒による環化付加反応

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​原著論文
Publications

  1. “Carbostannylation of Alkynes Catalyzed by an Iminophosphine-Palladium Complex” Shirakawa, E.; Yoshida, H.; Kurahashi, T.; Nakao, Y.; Hiyama, T. J. Am. Chem. Soc. 1998, 120, 2975.

  2. “Palladium-Iminophosphine-Catalyzed Alkynylstannylation of Alkynes” Yoshida, H.; Shirakawa, E.; Kurahashi, T.; Nakao, Y.; Hiyama, T. Organometallics 2000, 19, 5671. 

  3. “Diphenylphosphinophenolate: a Ligand for the Palladium-Catalyzed Silylation of Aryl Halides Activating Simultaneously both Palladium and Silicon” Shirakawa, E.; Kurahashi, T.; Yoshida, H.; Hiyama, T. Chem. Commun. 2000, 1895. 

  4. “Geminal Difunctionalization of Alkenylidene-Type Carbenoids by Using Interelement Compounds” Hata, T.; Kitagawa, H.; Masai, H.; Kurahashi, T.; Shimizu, M.; Hiyama, T. Angew. Chem. Int. Ed. 2001, 40, 790.

  5.  “Novel Synthesis of 2,3-Bisboryl-1,3-dienes from 1-Bromo-1-lithioethene and 1,1-Bisborylalkenes” Shimizu, M.; Kurahashi, T.; Hiyama, T. Synlett, 2001, 1006. 

  6.  “1-Silyl-1-boryl-2-alkenes: Reagents for Stereodivergent Allylation Leading to 4-Oxy-(E)-1- alkenylboronates and 4-Oxy-(Z)-1-alkenylsilanes” Shimizu, M.; Kitagawa, H.; Kurahashi, T.; Hiyama, T. Angew. Chem. Int. Ed. 2001, 40, 4283. 

  7.  “Geminal Dimetalation of Alkylidene-Type Carbenoids with Silylboranes and Diborons” Kurahashi, T.; Hata, T.; Masai, H.; Kitagawa, H.; Shimizu, M.; Hiyama, T. Tetrahedron 2002, 58, 6381. 

  8. “gem-Silylborylation Approach for Tri- and Tetrametalmethanes: The First Synthesis of Boryl(germyl)(silyl)(stannyl)methanes” Shimizu, M.; Kurahashi, T.; Shimono, K.; Hiyama, T. J. Organomet. Chem. 2003, 686, 286. 

  9. “gem-Silylborylation of an sp Carbon: Novel Synthesis of 1-Boryl-1-silylallenes” Shimizu, M.; Kurahashi, T.; Kitagawa, H.; Hiyama, T. Org. Lett. 2003, 5, 225. 

  10. “Facile Synthesis of Dendralenes Based on the Cross-coupling Reaction of 2,3-Bis(pinacolato)boryl-1,3-butadiene” Shimizu, M.; Tanaka, K.; Kurahashi, T.; Shimono, K.; Hiyama, T. Chem. Lett. 2004, 33, 1066. 

  11. “Stereoselective Cross-Coupling Reaction of 1,1-Diboryl-1-alkenes with Electrophiles: A Highly Stereocontrolled Approach to 1,1,2-Triaryl-1-alkenes” Shimizu, M.; Nakamaki, C.; Shimono, K.; Schelper, M.; Kurahashi, T.; Hiyama, T. J. Am. Chem. Soc. 2005, 127, 12506.

  12. “Cyclopentenones from a Novel [4+1] Cocyclization of Methylenecyclopropanes with Fischer Carbenechromium Complexes” Kurahashi, T.; de Meijere, A. Synlett, 2005, 805.

  13. “[5+1] Cocyclization of (Cyclopropylmethylene)cyclopropanes and Other Vinyl-Cyclopropanes with Carbon Monoxide Catalyzed by Octacarbonyldicobalt” Kurahashi, T.; de Meijere, A. Synlett, 2005, 2619. 

  14. “Cyclopropyl Building Blocks for Organic Synthesis, Part 121. C–C Bond Activation by Octacarbonyldicobalt: [3+1] Cocyclizations of Methylenecyclopropanes with Carbon Monoxide” Kurahashi, T.; de Meijere, A. Angew. Chem. Int. Ed. 2005, 44, 7881.　

  15. “Synthesis and Applications of 1,1-Diborylated Cyclopropanes: Facile Route to 1,2-Diboryl-3-methylenecyclopentenes” Shimizu, M.; Nagao, I.; Shimono, K.; Kurahashi, T.; Hiyama, T. Chem. Lett. 2006, 35, 1222.

  16. “Syntheses and Properties of Enantiomerically Pure Higher (n > 7) n-2 Triangulanedimethanols and σ- [n] Helicenes” de Meijere, A.; Khlebnikov, A. E.; Kozhushkov, S. I; Kurahashi, T.; Miyazawa, K. Chem. Euro. J. 2006, 12, 5697.

  17. “Intermolecular Rhodium-Catalyzed Carbometalation/Heck-Type Reaction in Water” Kurahashi, T.; Shinokubo, H.; Osuka, A. Angew. Chem. Int. Ed. 2006, 45, 6336.
    Highlighted in Organic Chemistry Portal.

  18. “1,1'-Linked Cyclopropane Derivatives: The Helical Conformation of Quinquecyclopropanol” Kurahashi, T.; Kozhushkov, S. I.; Schill, H.; Meindl, K.; Ruhl, S.; de Meijere, A. Angew. Chem. Int. Ed. 2007, 46, 6545.

  19. “Facile Synthesis and Palladium-Catalyzed Cross-Coupling Reactions of 2,3-Bis(pinacolatoboryl)-1,3-butadiene” Shimizu, M.; Kurahashi, T.; Nagao, I.; Kiyomoto, S. I.; Hiyama, T. Chem. Asia J. 2007, 2, 1400.

  20. “Diels-Alder Reaction of 2,3-Bis(pinacolatoboryl)-1,3-butadiene: Facile Preparation of 1,2-bis(pinacolatoboryl)cyclohexenes and-1,4-cyclohexadiene” Shimizu, M.; Shimono, K.; Kurahashi, T.; Nagao, I.; Hiyama, T. Bull. Chem. Soc. Jp. 2008, 81, 518.

  21. “Nickel-Catalyzed Decarbonylative Addition of Phthalimides to Alkynes” Kajita, Y.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2008, 130, 6058.   
    Highlighted as the Most Read Articles.
    Highlighted in SYNFACTS, 2008, 764.

  22. “Nickel-Catalyzed Decarbonylative Addition of Anhydrides to Alkynes” Kajita, Y.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2008, 130, 17226.
    Highlighted as the Most Read Articles.

  23. “Diastereoselective Nucleophilic Cyclopropanation of 1,2-Diketones and α-Ketoimines with Bis(iodozincio)methane” Nomura, K.; Asano, K.; Kurahashi, T.; Matsubara, S. Heterocycles 2008, 76, 1381.

  24. “Nickel-Catalyzed [4+2] Cycloaddition of Enones with Alkynes” Koyama, I.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2009, 131, 1350.    

  25. “Nickel-Catalyzed Decarboxylative Carboamination of Alkynes with Isatoic Anhydrides” Yoshino, Y.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2009, 131, 7494.   
    Highlighted in SYNFACTS, 2009, 833.

  26. “Nickel-Catalyzed Cycloaddition of Salicylic acid Ketals to Alkynes via Elimination of Ketones” Ooguri, A.; Nakai, K.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2009, 131, 13194.  
    Highlighted as the Most Read Articles.

  27. “Nickel-Catalyzed [4+2] Cycloaddition of Alkynes to Carbonylsalicylamides via Elimination of Isocyanates”  Yoshino, Y.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2010, 39, 896.

  28. “Decarbonylative Cycloaddition of Phthalimides with 1,3-Dienes” Fujiwara, K.; Kurahashi, T.; Matsubara, S. Org. Lett. 2010, 12, 4548. 

  29. “Selective Synthesis of Trienes and Dienes via Nickel-Catalyzed Intermolecular Cotrimerization of Acrylates and Alkynes” Horie, H.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2010, 46, 7229. 

  30. “Nickel-Catalyzed [2+2+1] Cycloaddition of Alkynes, Acrylates and Isocyanates” Ozawa, T.; Horie, H.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2010, 46, 8055.

  31. “Nickel-Catalyzed Decarbonylative Cycloaddition of Phthalic Anhydrides with 1,3-Diene” Fujiwara, K.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2011, 40, 322. 

  32. “Nickel-Catalyzed Cycloadditions of Benzoxazinones with Alkynes: Synthesis of Quinolines and Quinolones” Maizuru, N.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2011, 40, 375. 

  33. “Nickel-Catalyzed Cycloaddition of Anthranilic Acid Derivatives to Alkynes” Maizuru, N.; Inami, T.; Kurahashi, T.; Matsubara, S. Org. Lett. 2011, 13, 1206. 

  34. “Nickel-Catalyzed Cycloadditions of Thiophthalic Anhydrides with Alkynes” Inami, T.; Kurahashi, T.; Matsubara, S. Org. Lett. 2011, 13, 1912.

  35. “Decarbonylative Cycloaddition of Phthalic Anhydrides with Allenes” Ochi, Y.; Kurahashi, T.; Matsubara, S. Org. Lett. 2011, 13, 1374.     

  36. “Nickel-Catalyzed Intermolecular Codimerization of Acrylates and Alkynes” Horie, H.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2011, 47, 2658. 

  37. “Nickel-Iminophosphine-Catalyzed [4+2] Cycloaddition of Enones with Allenes: Synthesis of Highly Substituted Dihydropyrans” Sako, S.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2011, 47, 6150.

  38. “Nickel-Catalyzed [3 + 2] Cycloaddition of a,b-Unsaturated Ketones with Vinyloxiranes“ Sako, S.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2011, 40, 808.

  39.  “Nickel-Catalyzed Cycloaddition of o-Arylcarboxybenzonitriles and Alkynes via Cleavage of Two Carbon–Carbon s Bonds“ Nakai, K.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2011, 133, 11066.
    Highlighted as the Most Read Articles.
    Highlighted in SYNFACTS, 2011, 1065.

  40. “Nickel-Catalyzed Cycloaddition of Aromatic (O-Benzyl)Ketoximes with Alkynes to Produce Isoquinoline and Isoquinoline N-Oxide Derivatives” Yoshida, Y.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2011, 40, 1140.
    Highlighted as Editor’s Choice Article.

  41. “Methylenecyclopropanes in [4 + 1] Cycloaddition with Enones” Inami, T.; Sako, S.; Kurahashi, T.; Matsubara, S. Org. Lett. 2011, 13, 3837.

  42. “Dehydrogenative Diels-Alder Reaction” Ozawa, T.; Kurahashi, T.; Matsubara, S. Org. Lett. 2011, 13, 5390.

  43. “Nickel-Catalyzed Heteroannulation of o-Haloanilines with Alkynes” Yoshida, Y.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2011, 40, 1067.

  44. “Nickel-Catalyzed Decarboxylative Polymerization of 6-Alkynyl Isatoic Anhydride” Yoshino, Y.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2011, 40, 1240.

  45. “Methylenecyclopropane as C1 Synthetic Units: [1 + 4] Cycloaddition by Nickel Catalyst” Inami, T.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2011, 47, 9711.

  46. “Nickel-Catalyzed Cycloaddition of α,β,γ,δ-Unsaturated Ketones with Alkynes” Horie, H.; Kurahashi, T.; Matsubara, S. Angew. Chem. Int. Ed. 2011, 50, 8956. 
    Highlighted as Hot Paper.

  47. “Nickel-Catalyzed [4+2] Cycloaddition for Highly Substituted Arenas” Horie, H.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2012, 48, 3866.
    Highlighted in ChemistryViews.

  48. “Cationic Iron(III) Porphyrin Catalyzed [4+2] Cycloaddition of Unactivated Aldehydes with Simple Dienes” Fujiwara, K.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2012, 134, 5512.
    Highlighted as the Most Read Articles.
    Highlighted as Synfact of the Month in SYNFACTS, 2012, 625.
    解説記事掲載　化学 2012年10月号59頁.

  49. “Manganese Porphyrin Catalyzed Cycloisomerization of Enynes” Ozawa, T.; Kurahashi, T.; Matsubara, S. Org. Lett. 2012, 14, 5390.
    Highlighted as the Most Read Articles.

  50. “Nickel-Catalyzed Cycloaddition of α,β-Unsaturated Oximes with Alkynes; Synthesis of Highly Substituted Pyridine Derivatives” Yoshida, Y.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2012, 41, 1498.
    Highlighted as Editor’s Choice Article.

  51. “Ruthenium Porphyrin Catalyzed Friedel–Crafts Type Reaction of Arenes with Imines” Terada, T.; Kurahashi, T.; Matsubara, S. Heterocycles 2012, 80, 2415.

  52. “Nickel-Catalyzed Decarbonylative Polymerization of 5-Alkynyl Phthalimides: a New Methodology for Preparation of Polyheterocycles” Takeuchi, M.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2012, 41, 1566.

  53. “Cobalt(III) Porphyrin Catalyzed Aza-Diels–Alder Reaction”  Wakabayashi, R.; Kurahashi, T.; Matsubara, S. Org. Lett. 2012, 14, 4794.

  54. “Nickel-Catalyzed Decarbonylative Alkylidenation of Phthalimides with Trimethylsilyl-Substituted Alkynes” Shiba, T.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2013, 135, 13636.  
    Highlighted as the Most Read Articles.

  55. “Synthesis of Quinolones by Nickel-Catalyzed Cycloaddition via Elimination of Nitrile” Nakai, K.; Kurahashi, T.; Matsubara, S. Org. Lett. 2013, 15, 856.

  56. “Nickel-Catalyzed Cycloaddition of Vinylcyclopropanes to Imines” Tombe, R.; Kurahashi, T.; Matsubara, S. Org. Lett. 2013, 15, 1791.
    Highlighted as the Most Read Articles.

  57. “Nickel-Catalyzed Decarbonylative /Decarboxylative Cycloaddition of Isatoic Anhydrides with Alkynes” Nakai, K.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2013, 42, 1238.

  58. “Cationic Iron(III) Porphyrin Catalyzed Dehydrative Friedel–Crafts Reaction of Alcohols with Arenes” Teranishi, S.; Kurahashi, T.; Matsubara, S. Synlett, 2013, 24, 2148.

  59. “Iron Corrole-Catalyzed [4+2] Cycloaddition of Dienes and Aldehydes” Kuwano, T.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2013, 42, 1241.

  60. “Synthesis of Phenanthrenes by Cationic Chromium(III) Porphyrin-Catalyzed Dehydration Cycloaromatization” Wakabayashi, R.; Kurahashi, T.; Matsubara, S. Synlett, 2013, 24, 2297.

  61. “[3+2] Cycloaddition of Aziridines with Alkenes Catalyzed by Cationic-Manganese-Porphyrin” Ozawa, T.; Kurahashi, T.; Matsubara, S. Synlett, 2013, 24, 2763.
    Highlighted in Organic Chemistry Portal.

  62. “Dicationic Platinum Porphyrin Catalyzed Cycloisomerization of Enynes” Hasegawa, M.; Kurahashi, T.; Matsubara, S. Tetrahedron Lett. 2013, 54, 6196.

  63. “Theoretical Mechanistic Study of Novel Ni(0)-Catalyzed [6-2+2] Cycloaddition Reactions of Isatoic Anhydrides with Alkynes: Origin of Facile Decarboxylation” Guan, W.; Sakaki, S.; Kurahashi, T.; Matsubara, S. Organometallics 2013, 32, 7564.

  64. “Nickel-Catalyzed Redox-Economical Coupling of Alcohols and Alkynes to Form Allylic Alcohols” Nakai, K.; Yoshida, Y.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2014, 136, 7797.
    Highlighted as the Most Read Articles.
    解説記事掲載　日経産業新聞　平成27年9月24日.

  65. “Diastereoselective Construction of Trans-Fused Octalone Framework via Ruthenium-Porphyrin-Catalyzed Cycloaddition” Terada, T.; Kurahashi, T.; Matsubara, S. Org. Lett. 2014, 16, 2594–2597.
    Highlighted as the Most Read Articles.
    Highlighted in SYNFACTS, 2014, 715.

  66. “Palladium Porphyrin Catalyzed Hydrogenation of Alkynes: Stereoselective Synthesis of cis-Alkenes” Nishibayashi, R.; Kurahashi, T.; Matsubara, S. Synlett, 2014, 25, 1287.
    Highlighted in Organic Chemistry Portal.

  67. “Rh(III) Porphyrin-Catalyzed Reactions via Activation of Alkynes” Hasegawa, M.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2014, 43, 1287.

  68. “Cobalt Porphyrin Catalyzed [3+2] Cycloaddition of Cyclopropanes and Carbonyl Compounds” Shiba, T.; Kurahashi, T.; Matsubara, S. Synlett, 2014, 25, 2005.

  69. “Regio- and Diastereoselective Nickel-Catalyzed Cycloaddition of Activated Cyclopropanes with Allenes” Tombe, R.; Iwamoto, T.; Kurahashi, T.; Matsubara, S. Synlett, 2014, 25, 2281.
    Highlighted as a Cluster Article.

  70. “Ruthenium-Porphyrin-Catalyzed [4+2] Cycloaddition of a,b-Unsaturated Imines and Aldehydes” Maeda, K.; Terada, T.; Iwamoto, T.; Kurahashi, T.; Matsubara, S. Org. Lett. 2015, 17, 5284.

  71. “Nickel-Catalyzed Dual C-C σ Bond Activation to Construct Carbocyclic Skeletons” Nakai, K.; Kurahashi, T.; Matsubara, S. Tetrahedron, 2015, 71, 4512.

  72. “Reasons Two Nonstrained C-C σ-Bonds Can Be Easily Cleaved in Decyanative [4+2] Cycloaddition Catalyzed by Nickel(0)/Lewis Acid Systems. Theoretical Insight” Gua, W.; Sakaki, S.; Kurahashi, T.; Matsubara, S. ACS Catal. 2015, 5, 1.  

  73. “Nickel-Catalysed Synthesis of Tetrasubstituted Vinyl Sulfides from Thiocarbamates and Internal Alkynes” Inami, T.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2015, 51, 1285.

  74. “A Triphenylamine with Two Phenoxy Radicals Having Unusual Bonding Patterns and a Closed-Shell Electronic State” Sakamaki, D.; Yano, S.; Kobashi, T.; Seki, S.; Kurahashi, T.; Matsubara, S.; Ito, A. Angew. Chem. Int. Ed. 2015, 28, 8267. 

  75. “Nickel-Catalyzed Intermolecular Carboiodination of Alkynes with Aryl Iodides” Takahashi, T.; Kuroda, D.; Kuwano, T.; Kurahashi, T.; Matsubara, S. Chem. Commun. 2018, 54, 12750. 
    Highlighted in Chemistry Views.

  76. “Ligand-Controlled Behavior of Ag(I)-π Complex as σ-Lewis Acid” Maeda, K.; Takahashi, T.; Tomifuji, R.; Hirao, N.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2018, 47, 532. 

  77. “FeCl3 as an Ion-Pairing Lewis Acid Catalyst. Formation of Highly Lewis Acidic FeCl2+ and Thermodynamically Stable FeCl4– To Catalyze the Aza-Diels–Alder Reaction with High Turnover Frequency” Tomifuji, R.; Maeda, K.; Takahashi, T.; Kurahashi, T.; Matsubara, S. Org. Lett. 2018, 20, 7474. 
    Highlighted in Organic Chemistry Portal.

  78. “Diastereoselective Synthesis of 1,3-Oxazolidines via Cationic Iron Porphyrin-catalyzed Cycloaddition of Aziridines with Aldehydes” Teranishi, S.; Maeda, K.; Kurahashi, T.; Matsubara, S. Org. Lett. 2018, 20, 2593.
    Highlighted in Organic Chemistry Portal.

  79. “Cationic Cobalt Porphyrin-Catalyzed Allylation of Aldehydes with Allyltrimethylsilanes” Tomifuji, R.; Masuda, S.; Kurahashi, T.; Matsubara, S. Org. Lett. 2019, 21, 3834.

  80. “Asymmetric Aza‐Diels–Alder Reaction with Ion‐Paired—Iron Lewis Acid—Brønsted Acid Catalyst” Tomifuji, R.; Kurahashi, T.; Matsubara, S. Chem. Eur. J. 2019, 25, 8987.
    Highlighted as Hot Paper.
    Highlighted in SYNFACTS, 2019, 1231.

  81. “Chlorotrifluoromethylation of Terminal Olefins by Atom Transfer-Type Radical Reaction Catalyzed by Cobalt Complexes” Maeda, K.; Kurahashi, T.; Matsubara, S. Eur. J. Org. Chem. 2019, 4613.

  82. “Nickel-Catalyzed [5+2] Cycloaddition of 10π-Electron Aromatic Benzothiophenes with Alkynes To Form Thermally Metastable 12π-Electron Nonaromatic Benzothiepines” Inami, T.; Takahashi, T.; Kurahashi, T.; Matsubara, S. J. Am. Chem. Soc. 2019, 141, 12541.

  83. “Nickel-Catalyzed Intermolecular Carbobromination of Alkynes” Takahashi, T.; Kurahashi, T.; Matsubara, S. ACS Catal. 2020, 10, 3773.

  84. “Cu(II) Porphyrin-Catalyzed Coupling of Alkyl Tosylates and Grignard Reagents” Matsuoka, I.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2020, 49, 442.

  85. “Synthesis, Characterization and Chemical Behavior of Disulfide-Bearing Mononuclear Transition Metal Complexes with the Rigid Structure” Maeda, K.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2021, 50, 1883.

  86. “Catalytic Aerobic Oxidation of Alkenes with Ferric Boroperoxo Porphyrin Complex; Reduction of Oxygen by Iron Porphyrin” Kimura, K.; Murano, S.; Kurahashi, T.; Matsubara, S. Bull. Chem. Soc. Jp. 2021, 94, 2493.
    Highlighted as Selected Paper.

  87. “Ni-Catalyzed Dearomative Cycloaddition of Alkynes to 10π Aromatic Benzothiophenes: Elucidation of Reaction Mechanism” Takahashi, T.; Kurahashi, T.; Matsubara, S. Bull. Chem. Soc. Jp. 2021, 94, 2727.
    Highlighted as BSCJ Award Article.

  88. “Multiple Activation Catalyst for Asymmetric [4 + 2] Cycloaddition of Aldehydes with Dienes” Tomifuji, R.; Murano, S.; Teranishi, S.; Kuroda, D.; Kurahashi, T.; Matsubara, S. Synlett, 2021, 32, 1943.

  89. “A New Synthetic Route to (Trifluoromethyl)quinolines: Nickel-Catalyzed Insertion of an Alkyne into an Aromatic C–S Bond by Formation of a Thianickelacycle and Thermal Desulfidation” Inami, T.; Kurahashi, T.; Matsubara, S. Synlett, 2021, 32, 1948.
    Highlighted in Synform.

  90. “FeBr3-Catalyzed Fully Intermolecular [2+2+2] Cycloaddition of Alkenes” Tomifuji, R.; Murano, S.; Kurahashi, T.; Matsubara, S. Chem. Lett. 2021, 12, 2018.

  91. “Aerobic Direct Dioxygenation of Terminal/Internal Alkynes to α-Hydroxyketones by an Fe Porphyrin Catalyst” Kimura, K.; Kurahashi, T.; Matsubara, S. Chem. Eur. J. 2021, 16, 3615.

総説
Reviews

  1. “Novel Bifunctional Synthetic Reagents: gem-Dimetallic Compounds Derived from Carbenoid Reagents and Interelement Compounds” Shimizu, M.; Kurahashi, T.; Hiyama, T. J. Syn. Org. Chem. Jp. 2001, 59, 1062.

  2. “Applications of Fischer Carbenemetal Complexes in Organic Synthesis.” Wu, Y. T.; Kurahashi, T.; de Meijere, A. J. Organomet. Chem. 2005, 690, 5900.

  3. “Syntheses of Heterocycles by Nickel-catalyzed Substitution Reaction-Development of [6-2+2] Reaction” Matsubara, S.; Kurahashi, J. Syn. Org. Chem. Jp. 2010, 68, 33.

  4. “Ni-Catalyzed C–C Bond Formation with α,β-Unsaturated Carbonyl Compounds and Alkynes” Kurahashi, T. Bull. Chem. Soc. Jpn. 2014, 87, 1058. 

  5. “Nickel-Catalyzed Reactions Reactions Directed toward the Formation of Heterocycles” Matsubara, S.; Kurahashi, T. Acc. Chem. Res. 2015, 48, 1703.
     

著書
Books and Chapters

  1. “Simultaneous C–C and Other Bond Formation” A. de Meijere and T. Kurahashi, Comprehensive Organometallic Chemistry, Vol. 11, Pergamon Press, 2005.

  2. “[4+2] Cycloaddition via Metallacycles” T. Kurahashi and S. Matsubara, Transition-Metal-Mediated Aromatic Ring Construction, Wiley, 2012. 
     

KURAHASHI Lab

〒669-1330 兵庫県三田市学園上ケ原

関西学院大学 神戸三田キャンパス​

4号館 理学部化学科1階

kurahashi＠kwansei.ac.jp

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